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CHEMICAL PRODUCT & COMPANY IDENTIFICATION

PRODUCT NAME: .................................... PROPYLENE GLYCOL INDUSTRIAL

PRODUCT CODE: ...................................... 70511

EFFECTIVE DATE: .................................... 05/23/03

COMPANY IDENTIFICATION: ............... The Dow Chemical Company, Midland, MI 48674

EMERGENCY TELEPHONE NUMBER: . 24-HOUR EMERGENCY PHONE NUMBER 989-636-4400

...................................................................... Customer Information Center: 800-258-2436

COMPOSITION/INFORMATION ON INGREDIENTS

Propylene glycol

HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW: ....................... Colorless, odorless liquid. Toxic fumes released in fire situations.

POTENTIAL HEALTH EFFECTS: ................. (See Section 11 for toxicological data.)

EYE: ...................................................................... May cause slight transient (temporary) eye irritation. Corneal injury is unlikely. Mists may

SKIN: .................................................................... Prolonged contact is essentially nonirritating to skin. A single prolonged skin exposure is not

INGESTION: ........................................................ Single dose oral toxicity is considered to be extremely low. No hazards anticipated from

INHALATION: .................................................... At room temperature, vapors are minimal due physical properties. Mists may cause irritation

SYSTEMATIC: .................................................... (OTHER TARGET ORGAN) EFFECTS: Repeated excessive ingestion may cause central

CANCER INFORMATION: ............................... Did not cause cancer in long-term animal studies.

TERATOLOGY (BIRTH DEFECTS): .............. Birth defects are unlikely. Exposures having no adverse effects on the mother should have

REPRODUCTIVE EFFECTS: ............................ In animal studies, has been shown not to interfere with reproduction.

FIRST AID

EYE: ...................................................................... Flush eyes with plenty of water.

SKIN: .................................................................... Wash off in flowing water or shower.

INGESTION: ........................................................ No adverse effects anticipated by this route of exposure incidental to proper industrial

INHALATION: .................................................... Remove to fresh air if effects occur. Consult a physician

NOTE TO PHYSICIAN: .................................... No specific antidote. Supportive care. Treatment based on judgment of the physician in

FIRE FIGHTING MEASURES

FLASH POINT: .................... 218°F, 103°C

METHOD USED: ................ PMCC

FLAMMABLE LIMITS ...... LFT: 2.6%

LFL: ....................................... 2.6%

UFL: ....................................... 12.5%

HAZARDOUS COMBUSTION PRODUCTS: During a fire, smoke may contain the original material in addition to unidentified toxic

and/or irritating compounds. Hazardous combustion products may include and are not limited to: aldehydes, carbon monoxide.

OTHER FLAMMABILITY INFORMATION: Violent steam generation or eruption may occur upon application of direct water stream

to hot liquids. Spills of these organic liquids on hot fibrous insulations may lead to lowering of the autoignition temperatures

possibly resulting in spontaneous combustion.

EXTINGUISHING MEDIA: Water fog or fine spray, carbon dioxide, dry chemical, foam. Alcohol resistant foams (ATC type) are

preferred if available. General purpose synthetic foams (including AFFF) or protein foams may function, but much less effectively.

Do not use direct water stream. Will spread fire.

MEDIA TO BE AVOIDED: Do not use direct water stream.

FIRE FIGHTING INSTRUCTIONS: Keep people away. Isolate fire area and deny unnecessary entry. Burning liquids may be moved by

flushing with water to protect personnel and minimize property damage. Burning liquids may be extinguished by dilution with water.

Do not use direct water stream. May spread fire.

PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: Wear positive-pressure, self-contained breathing apparatus (SCBA) and protective

fire-fighting clothing (including fire-fighting helmet, coat, pants, boots, and gloves). If protective equipment is not available or not

used, fight fire from a protected location or safe distance.

Safety Concerns

Material Safety Data Sheet

BOSS CHILL PG

Canadian Centre for Occupational Health and Safety

Issue: 2001-4 (November, 2001)

***MATERIAL SAFETY DATA***

DATE PRINTED 10/09/03

CAS# 000057-55-6 > 99%

cause eye irritation.

likely to result in the material being absorbed through skin in harmful amounts. Repeated

exposures may cause flaking and softening of skin. May be absorbed in potentially harmful

amounts when applied in large quantities to severe burns (second or third degree) over large

areas of the body as part of a cream or other topical application. Absorption under such

circumstances can elevate serum osmolality and may result in osmotic shock.

swallowing small amounts incidental to normal handling operations.

of upper respiratory tract.

nervous system effects.

no effect on the fetus.

handling.

response to reactions of the patient.

MSDS

MSD: 000248

2-2